Abstract Two deep (> 2.5 m) cores were taken from sites in Mangere Inlet, Manukau Harbour, New Zealand. Depth profiles of polycyclic aromatic hydrocarbons (PAHs) showed that from c. 1950 to the present, total PAH mostly comprised unsubstituted compounds (having molecular weight 178, 202, 228, 252, and 276), indicative of inputs deriving from combustion and pyrolysis of fossil fuels. Total PAH in deeper sediments of both cores predominantly comprised perylene. Maximum concentrations of total PAH in the cores were 1521 and 574 ng g-1 (dry weight) and were below levels regarded as injurious to aquatic life. Deposition fluxes of 1400-4900 and 1300-2200 ng cm-2 yr-1 were found in post-1950 sediments of the two cores. Although these fluxes are similar to those of other sediments in polluted environments, their magnitudes result from very high sedimentation rates and moderate PAH concentrations, rather than low sedimentation rates and high concentrations.
Keywords PAH; urban run-off; deposition flux; sediment cores; organic contaminants
New Zealand Journal of Marine and Freshwater Research, 1995: Vol. 29: 107-116
0028-8330/95/2901-0107 $2.50/0 (c) The Royal Society of New Zealand 1995
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